this is sooooo wrong. triggers need to be fast. web services can be slow for any number of reasons, for example, the web server that hosts it is down.
do you really want your db to lock up for 30 sec on each insert while your trigger waits for some web server to timeout? [

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the only thing i can think of that might be worse would be popping a messagebox from a trigger. or perhaps calling Environment.Exit() [

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